You will find answer here.
Short answer is:
1.Capture some successfully authorized request using Fiddler tool.
2.Choose "Inspectors" -> "Headers" tab.
3.Pay attention at "Cookies / Login" section, "Authorization" header.
If the Authorization token begins with "YII" then Kerberos is used, but if it begins with "TlR" then Kerberos is not used.
For example Kerberos:
Authorization: Negotiate YIIVDAYGKwYBE...
Not Kerberos:
Authorization: Negotiate TlRMTVNTUA...
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