Using numpy, you could use np.corrcoef:
In [88]: import numpy as np
In [89]: np.corrcoef([[0.1, .32, .2, 0.4, 0.8], [.23, .18, .56, .61, .12], [.9, .3, .6, .5, .3], [.34, .75, .91, .19, .21]])
Out[89]:
array([[ 1. , -0.35153114, -0.74736506, -0.48917666],
[-0.35153114, 1. , 0.23810227, 0.15958285],
[-0.74736506, 0.23810227, 1. , -0.03960706],
[-0.48917666, 0.15958285, -0.03960706, 1. ]])
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