Depending on your version of cron, you should be able to do (for hours, say):
1-23/2
Going by the EXTENSIONS section in the crontab(5) manpage:
Ranges can include "steps", so "1-9/2" is the same as "1,3,5,7,9".
For a more portable solution, I suspect you just have to use the simple list:
1,3,5,7,9,11,13,15,17,19,21,23
But it might be easier to wrap your command in a shell script that will immediately exit if it's not called in an odd minute.
与恶龙缠斗过久,自身亦成为恶龙;凝视深渊过久,深渊将回以凝视…