AFAIK, you have to convert it to grayscale and then threshold it to binary.
1. Read the image as a grayscale image
If you're reading the RGB image from disk, then you can directly read it as a grayscale image, like this:
// C
IplImage* im_gray = cvLoadImage("image.jpg",CV_LOAD_IMAGE_GRAYSCALE);
// C++ (OpenCV 2.0)
Mat im_gray = imread("image.jpg",CV_LOAD_IMAGE_GRAYSCALE);
2. Convert an RGB image im_rgb
into a grayscale image: Otherwise, you'll have to convert the previously obtained RGB image into a grayscale image
// C
IplImage *im_rgb = cvLoadImage("image.jpg");
IplImage *im_gray = cvCreateImage(cvGetSize(im_rgb),IPL_DEPTH_8U,1);
cvCvtColor(im_rgb,im_gray,CV_RGB2GRAY);
// C++
Mat im_rgb = imread("image.jpg");
Mat im_gray;
cvtColor(im_rgb,im_gray,CV_RGB2GRAY);
3. Convert to binary
You can use adaptive thresholding or fixed-level thresholding to convert your grayscale image to a binary image.
E.g. in C you can do the following (you can also do the same in C++ with Mat and the corresponding functions):
// C
IplImage* im_bw = cvCreateImage(cvGetSize(im_gray),IPL_DEPTH_8U,1);
cvThreshold(im_gray, im_bw, 128, 255, CV_THRESH_BINARY | CV_THRESH_OTSU);
// C++
Mat img_bw = im_gray > 128;
In the above example, 128 is the threshold.
4. Save to disk
// C
cvSaveImage("image_bw.jpg",img_bw);
// C++
imwrite("image_bw.jpg", img_bw);
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