Hmmm... Like This one ?
Private Sub Button3_Click(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles Button3.Click
Dim fetchDGVHeaders(DataGridView1.ColumnCount) As String
For a = 0 To DataGridView1.ColumnCount - 1
fetchDGVHeaders(a) = DataGridView1.Columns(a).Name
MsgBox(fetchDGVHeaders(a))
Next
INSERT_INTO_DB("INSERT INTO DBHeaders(MEaw,MEow,MEow_MEow)VALUES('" & fetchDGVHeaders(0) & "','" & fetchDGVHeaders(1) & "','" & fetchDGVHeaders(2) & "','" & fetchDGVHeaders(3) & "')")
End Sub
Fetch the current DataGridView Headers then store it to other table
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