In scala you do it in similar way like in python but you need to use map and reduce functions:
val sparkSession = SparkSession.builder().getOrCreate()
import sparkSession.implicits._
val df1 = List("a,b", "b,c", "c,d").toDF("col1","col2")
val df2 = List("1,2", "2,c", "3,4").toDF("col1","col2")
val columnsdf1 = df1.columns
val columnsdf2 = df2.columns
val joinExprs = columnsdf1
.zip(columnsdf2)
.map{case (c1, c2) => df1(c1) === df2(c2)}
.reduce(_ && _)
val dfJoinRes = df1.join(df2,joinExprs)
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