I think you want padding in the ttk notebook's tabs?
In which case you can use a custom style, which you can adjust to your taste for colors padding etc.
import tkinter as tk
from tkinter import ttk
root = tk.Tk()
style = ttk.Style()
style.theme_create( "MyStyle", parent="alt", settings={
"TNotebook": {"configure": {"tabmargins": [2, 5, 2, 0] } },
"TNotebook.Tab": {"configure": {"padding": [100, 100] },}})
style.theme_use("MyStyle")
a_notebook = ttk.Notebook(root, width=200, height=200)
a_tab = ttk.Frame(a_notebook)
a_notebook.add(a_tab, text = 'This is the first tab')
another_tab = ttk.Frame(a_notebook)
a_notebook.add(another_tab, text = 'This is another tab')
a_notebook.pack(expand=True, fill=tk.BOTH)
tk.Button(root, text='Some Text!').pack(fill=tk.X)
root.mainloop()
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