Not an Oracle expert, but you are supposed to be able to do it without altering the session with
SELECT * FROM my_data SORT by NLSSORT(title,’NLS_SORT=BINARY_AI’)
where you can change the NLS_SORT=
to fit your needs (here are the list of values)
Keep in mind that docs says that this will force table scan, so it might be beneficial to filter them first (but if you are selecting all the table scan is what you are going to use anyway).
The reason why SQL Developer exhibits different behaviour is probably because it changes the session.
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